ADSORPTION EQUILIBRIUM STUDIES OF URANIUM (VI) ONTO CROSS-LINKED CHITOSAN-CITRIC ACID

HO THI YEU LY1, NGUYEN VAN SUC1, VO QUANG MAI2, NGUYEN MONG SINH3
1 HCM City University of Technical Education
2 Saigon University
3 Lam Dong Union of Science and Technology Associations

Main Article Content

Abstract

Investigation of U(VI) adsorption by the cross- linked chitosan with citric acid was conduced by bath method. Effect of parameters such as pH, contact time, adsorbent dosage and other metal cations was determined. The maximum adsorption capacity of U(VI) at pH 4 was found to be 243.90 mg U(VI)/g cross-linked chitosan - citric acid after 300 min of contact time. The Langmuir and Freundlich isotherm models were used to describe adsorption equilibrium. The correction values, R2 of two models were found to be 0.993 and 0.989, respectively. Therefore, it could be concluded that the adsorption equilibrium for U(VI) was followed the Langmuir and the Freundlich isotherm models.

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References

[1] E. Guibal C., Milot J.M., Tobin, Metal-anion sorption by chitosan beads: equilibrium and kinetic studies, Ind. Eng. Chem. Res. 37, pp. 1454 – 1463, 1998.
[2] E. Guibal I., Saucedo J., Roussy Ch., Roulph and Le Cloirec, Uranium sorption by glutamate glucan: Amodified chitosan Part II: Kinetic studies, Water SA, 19 (2) pp. 119-126, 1993.
[3] Ethena W., Merrill D. H., and David M. G., Metal complexation of chitosan and its glutaraldehyde cross-linked derivative, Carbohydrate Res. 324, pp. 1189-1201, 2007.
[4] Guibal E., Saucedo I., Jansson-charier M., Delanghe B., Le Cloirec P., Uranium and vanadium sorption by chitosan and derivatives, Wat Sci Technol., 30 (9), pp. 183-190, 1994.
[5] Ho Thi Yeu Ly, Nguyen Mong Sinh, Nguyen Van Suc, Adsorption of Pb(II) by crooslinked chitosan: kinetics and equilibrium studies. The 7th scientific conference, University of science-Ho Chi Minh City, 2010.
[6] Ho Thi Yeu Ly, Nguyen Mong Sinh, Nguyen Van Suc, Adsorption of cadimium (II) in aqueous solution on crooslinked chitosan, Journal of chemistry,T.48 (4C), pp. 300-305, 2010.
[7] Jansson-Charier M., Guibal E., Roussy J., Surjous R., Le Cloirec P., Dynamic removal of uranium by chitosan : influence of operating parameter Wat Sci Technol., 34 (10), pp. 169-177, 1996.
[8] Konstantinou M., and Pashalidis I., Speciation and spectrophotometric determination of uranium in seawater, Mediterranean Marine Sci., 5(1), 55-60, 2004.
[9] Martha B., Adsorption of metallic ions onto chitosan: equilibrium and kinetic studies, Licentiate thesis, Royal Institute of Technology, 2008.
[10] Pradip K.D., Joydeep D., Tripathi V. S, Chitin and chitosan: Chemistry, properties and applications, J. Sci.& Indus. Res., 63, pp. 20 – 31, 2004.
[11] Riccardo A.A., Muzzarelli M., Peter G., Chitin Handbook, Atec Edizioni Via San Martino IT-63013 Grottammare AP, Italy, 1997, pp. 405-451.
[12] Roberts G.A.F., and Taylor K.E., Chitosan Gels, the formation of gels by a reaction of chitosan with glutaraldehyde, Maromol.Chem., pp. 190 951, 1989.
[13] Takashi S., Takao H., and Akira N., Adsorption of uranium by chitin phosphate and chitosan phosphate, Agric. Biol. Chem, 45 (10), pp. 2191-2195, 1981.
[14] Veleshoko A.N., Rumyantseva E.V., Kulyukhin S.A., Veleshoko I.E., Vikhoreva G.A. and Lobanov N.S., Sorption of U(VI) from sulfate solutions with spherically granulated chitosans, Radiochem. 50(5), pp. 515-522, 2008.
[15] Wan Ngah W. S., Endud C. S., and Mayanar R., Adsorption of copper (II) ions onto chitosan and cross-linked chitosan beads, Material Chem.50, pp. 233 -242, 2001.
[16] Wan Ngah W. S., Ghani S. A., and Hoon L. L., Comparative adsorption of lead (II) on flake and bead-types of chitosan. J. Chinese Chem.Soc. 49, pp. 625-628, 2002.
[17] Wang G., Liu J., Wang X., Xie Z., Deng N., Adsorption of uranium(VI) from aqueous solution onto cross-linked chitosan J. Hazard. Matt. 168, pp. 1053-1058, 2009.